Carbide Insert
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Cemented carbides are a class of hard materials used extensively for
cutting tools In the context of machining, a cutting tool or cutter is typically a hardened metal tool that is used to cut, shape, and remove material from a workpiece by means of machining tools as well as abrasive tools by way of shear deformation. The majori ...
, as well as in other industrial applications. It consists of fine particles of
carbide In chemistry, a carbide usually describes a compound composed of carbon and a metal. In metallurgy, carbiding or carburizing is the process for producing carbide coatings on a metal piece. Interstitial / Metallic carbides The carbides of th ...
cemented into a
composite Composite or compositing may refer to: Materials * Composite material, a material that is made from several different substances ** Metal matrix composite, composed of metal and other parts ** Cermet, a composite of ceramic and metallic materials ...
by a binder metal. Cemented carbides commonly use
tungsten carbide Tungsten carbide (chemical formula: WC) is a chemical compound (specifically, a carbide) containing equal parts of tungsten and carbon atoms. In its most basic form, tungsten carbide is a fine gray powder, but it can be pressed and formed into ...
(WC),
titanium carbide Titanium carbide, Ti C, is an extremely hard ( Mohs 9–9.5) refractory ceramic material, similar to tungsten carbide. It has the appearance of black powder with the sodium chloride ( face-centered cubic) crystal structure. It occurs in natur ...
(TiC), or
tantalum carbide Tantalum carbides (TaC) form a family of binary chemical compounds of tantalum and carbon with the empirical formula TaC''x'', where ''x'' usually varies between 0.4 and 1. They are extremely hard, brittle, refractory ceramic materials with metall ...
(TaC) as the aggregate. Mentions of "carbide" or "tungsten carbide" in industrial contexts usually refer to these cemented composites. Most of the time, carbide cutters will leave a better surface finish on a part and allow for faster machining than
high-speed steel High-speed steel (HSS or HS) is a subset of tool steels, commonly used as cutting tool material. It is often used in power-saw blades and drill bits. It is superior to the older high-carbon steel tools used extensively through the 1940s in tha ...
or other
tool steel Tool steel is any of various carbon steels and alloy steels that are particularly well-suited to be made into tools and tooling, including cutting tools, dies, hand tools, knives, and others. Their suitability comes from their distinctive har ...
s. Carbide tools can withstand higher temperatures at the cutter-workpiece interface than standard high-speed steel tools (which is a principal reason enabling the faster machining). Carbide is usually superior for the cutting of tough materials such as carbon steel or stainless steel, as well as in situations where other cutting tools would wear away faster, such as high-quantity production runs. In situations where carbide tooling is not required, high-speed steel is preferred for its lower cost.


Composition

Cemented carbides are
metal matrix composite In materials science, a metal matrix composite (MMC) is a composite material with fibers or particles dispersed in a metallic matrix, such as copper, aluminum, or steel. The secondary phase is typically a ceramic (such as alumina or silicon carb ...
s where carbide particles act as the aggregate and a metallic binder serves as the matrix (analogous to concrete, where a gravel aggregate is suspended in a cement matrix). The structure of cemented carbide is conceptually similar to that of a
grinding wheel Grinding wheels contains abrasive compounds for grinding and abrasive machining operations. Such wheels are also used in grinding machines. The wheels are generally made with composite material . This consists of coarse-particle aggregate pres ...
, but the abrasive particles are much smaller; macroscopically, the material of a carbide cutter appears homogeneous. The process of combining the carbide particles with the binder is referred to as
sintering Clinker nodules produced by sintering Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing ...
or
hot isostatic pressing Hot isostatic pressing (HIP) is a manufacturing process, used to reduce the porosity of metals and increase the density of many ceramic materials. This improves the material's mechanical properties and workability. The process can be used to pro ...
(HIP). During this process, the material is heated until the binder enters a liquid phase while the carbide grains (which have a much higher melting point) remain solid. At this elevated temperature and pressure, the carbide grains rearrange themselves and compact together, forming a porous matrix. The ductility of the metal binder serves to offset the brittleness of the carbide ceramic, resulting in the composite's high overall toughness and durability. By controlling various parameters, including grain size, cobalt content, dotation (e.g., alloy carbides) and carbon content, a carbide manufacturer can tailor the carbide's performance to specific applications. The first cemented carbide developed was
tungsten carbide Tungsten carbide (chemical formula: WC) is a chemical compound (specifically, a carbide) containing equal parts of tungsten and carbon atoms. In its most basic form, tungsten carbide is a fine gray powder, but it can be pressed and formed into ...
(introduced in 1927) which uses tungsten carbide particles held together by a cobalt metal binder. Since then, other cemented carbides have been developed, such as
titanium carbide Titanium carbide, Ti C, is an extremely hard ( Mohs 9–9.5) refractory ceramic material, similar to tungsten carbide. It has the appearance of black powder with the sodium chloride ( face-centered cubic) crystal structure. It occurs in natur ...
, which is better suited for cutting steel, and
tantalum carbide Tantalum carbides (TaC) form a family of binary chemical compounds of tantalum and carbon with the empirical formula TaC''x'', where ''x'' usually varies between 0.4 and 1. They are extremely hard, brittle, refractory ceramic materials with metall ...
, which is tougher than tungsten carbide.


Physical properties

The
coefficient of thermal expansion Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions. Temperature is a monotonic function of the average molecular kineti ...
of cemented tungsten carbide is found to vary with the amount of cobalt used as a metal binder. For 5.9% cobalt samples, a coefficient of 4.4 µm·m−1·K−1 was measured, whereas 13% cobalt samples have a coefficient of around 5.0 µm·m−1·K−1. Both values are only valid from to due to non-linearity in the thermal expansion process.


Applications


Inserts for metal cutting

Carbide is more expensive per unit than other typical tool materials, and it is more brittle, making it susceptible to chipping and breaking. To offset these problems, the carbide cutting tip itself is often in the form of a small insert for a larger
tipped tool A tipped tool is any cutting tool in which the cutting edge consists of a separate piece of material that is brazed, welded, or clamped onto a body made of another material. In the types in which the cutter portion is an indexable part clamped ...
whose shank is made of another material, usually carbon
tool steel Tool steel is any of various carbon steels and alloy steels that are particularly well-suited to be made into tools and tooling, including cutting tools, dies, hand tools, knives, and others. Their suitability comes from their distinctive har ...
. This gives the benefit of using carbide at the cutting interface without the high cost and brittleness of making the entire tool out of carbide. Most modern face mills use carbide inserts, as well as many lathe tools and
endmill An end mill is a type of milling cutter, a cutting tool used in industrial milling applications. It is distinguished from the drill bit in its application, geometry, and manufacture. While a drill bit can only cut in the axial direction, most m ...
s. In recent decades, though, solid-carbide endmills have also become more commonly used, wherever the application's characteristics make the pros (such as shorter cycle times) outweigh the cons (mentioned above). As well, modern turning (lathe) tooling may use a carbide insert on a carbide tool such as a boring bar, which are more rigid than steel insert holders and therefor less prone to vibration, which is of particular importance with boring or threading bars that may need to reach into a part to a depth many times the tool diameter.


Insert coatings

To increase the life of carbide tools, they are sometimes coated. Five such coatings are TiN (
titanium nitride Titanium nitride (TiN; sometimes known as Tinite) is an extremely hard ceramic material, often used as a physical vapor deposition (PVD) coating on titanium alloys, steel, carbide, and aluminium components to improve the substrate's surface prop ...
), TiC (
titanium carbide Titanium carbide, Ti C, is an extremely hard ( Mohs 9–9.5) refractory ceramic material, similar to tungsten carbide. It has the appearance of black powder with the sodium chloride ( face-centered cubic) crystal structure. It occurs in natur ...
), Ti(C)N (
titanium carbide-nitride Titanium nitride (TiN; sometimes known as Tinite) is an extremely hard ceramic material, often used as a physical vapor deposition (PVD) coating on titanium alloys, steel, carbide, and aluminium components to improve the substrate's surface prop ...
), TiAlN (
titanium aluminium nitride Titanium aluminium nitride (TiAlN) or aluminium titanium nitride (AlTiN; for aluminium contents higher than 50%) is a group of metastable hard coatings consisting of nitrogen and the metallic elements aluminium and titanium. Four important compos ...
) and AlTiN ( aluminium titanium nitride). (Newer coatings, known as DLC ( diamond-like carbon) are beginning to surface, enabling the cutting power of diamond without the unwanted chemical reaction between real diamond and iron.) Most coatings generally increase a tool's hardness and/or lubricity. A coating allows the cutting edge of a tool to cleanly pass through the material without having the material gall (stick) to it. The coating also helps to decrease the temperature associated with the cutting process and increase the life of the tool. The coating is usually deposited via thermal chemical vapor deposition (CVD) and, for certain applications, with the mechanical
physical vapor deposition Physical vapor deposition (PVD), sometimes called physical vapor transport (PVT), describes a variety of vacuum deposition methods which can be used to produce thin films and coatings on substrates including metals, ceramics, glass, and polym ...
(PVD) method. However, if the deposition is performed at too high temperature, an ''eta phase'' of a Co6W6C tertiary carbide forms at the interface between the carbide and the cobalt phase, which may lead to adhesion failure of the coating.


Inserts for mining tools

Mining and tunneling cutting tools are most often fitted with cemented carbide tips, the so-called "button bits". Artificial diamond can replace the cemented carbide buttons only when conditions are ideal, but as rock drilling is a tough job cemented carbide button bits remain the most used type throughout the world.


Rolls for hot-roll and cold-roll applications

Since the mid-1960s, steel mills around the world have applied cemented carbide to the rolls of their rolling mills for both hot and cold rolling of tubes, bars, and flats.


Other industrial applications

This category contains a countless number of applications, but can be split into three main areas: * Engineered components * Wear parts * Tools and tool blanks Some key areas where cemented carbide components are used: * Automotive components * Canning tools for
deep drawing Deep drawing is a sheet metal metal forming, forming process in which a sheet metal blank is radially drawn into a forming die by the mechanical action of a punch. It is thus a shape transformation process with material retention. The process is c ...
of two-piece cans * Rotary cutters for high-speed cutting of artificial fibres * Metal forming tools for
wire drawing Wire drawing is a metalworking process used to reduce the cross-section of a wire by pulling the wire through a single, or series of, drawing die(s). There are many applications for wire drawing, including electrical wiring, cables, tension-loa ...
and stamping applications * Rings and bushings typically for bump and seal applications * Woodworking, e.g., for sawing and planing applications * Pump pistons for high-performance pumps (e.g., in
nuclear Nuclear may refer to: Physics Relating to the nucleus of the atom: * Nuclear engineering *Nuclear physics *Nuclear power *Nuclear reactor *Nuclear weapon *Nuclear medicine *Radiation therapy *Nuclear warfare Mathematics *Nuclear space *Nuclear ...
installations) * Nozzles, e.g., high-performance nozzles for
oil drilling An oil well is a drillhole boring in Earth that is designed to bring petroleum oil hydrocarbons to the surface. Usually some natural gas is released as associated petroleum gas along with the oil. A well that is designed to produce only gas may ...
applications * Roof and tail tools and components for high wear resistance * Balls for
ball bearing A ball bearing is a type of rolling-element bearing that uses balls to maintain the separation between the bearing races. The purpose of a ball bearing is to reduce rotational friction and support radial and axial loads. It achieves this ...
s and
ballpoint pen A ballpoint pen, also known as a biro (British English), ball pen (Hong Kong, Indian and Philippine English), or dot pen (Nepali) is a pen that dispenses ink (usually in paste form) over a metal ball at its point, i.e. over a "ball point". ...
s


Non-industrial uses


Jewellery

Tungsten carbide has become a popular material in the bridal jewellery industry, due to its extreme hardness and high resistance to scratching. Given its brittleness, it is prone to chip, crack, or shatter in jewellery applications. Once fractured, it cannot be repaired.


History

The initial development of cemented and sintered carbides occurred in Germany in the 1920s.
ThyssenKrupp ThyssenKrupp AG (, ; stylized as thyssenkrupp) is a German industrial engineering and steel production multinational conglomerate. It is the result of the 1999 merger of Thyssen AG and Krupp and has its operational headquarters in Duisburg a ...
says n_
n_historical_present_tense">historical_present.html"_;"title="n_historical_present">n_historical_present_tense_"Sintered_tungsten_carbide_ Tungsten_carbide_(chemical_formula:_WC)_is_a_chemical_compound_(specifically,_a_carbide)_containing_equal_parts_of_tungsten_and_carbon_atoms._In_its_most_basic_form,_tungsten_carbide_is_a_fine_gray_powder,_but_it_can_be_pressed_and_formed_into__...
_was_developed_by_the_'Osram_study_society_for_electrical_lighting'_to_replace_diamonds_as_a_material_for_machining_metal._Not_having_the_equipment_to_exploit_this_material_on_an_industrial_scale,_Osram_sells_the_license_to_Krupp_at_the_end_of_1925._In_1926_Krupp_brings_sintered_carbide_onto_the_market_under_the_name_WIDIA_(acronym_and_initialism.html" "title="historical_present_tense.html" ;"title="historical_present.html" ;"title="n historical present">n historical present tense">historical_present.html" ;"title="n historical present">n historical present tense "Sintered
tungsten carbide Tungsten carbide (chemical formula: WC) is a chemical compound (specifically, a carbide) containing equal parts of tungsten and carbon atoms. In its most basic form, tungsten carbide is a fine gray powder, but it can be pressed and formed into ...
was developed by the 'Osram study society for electrical lighting' to replace diamonds as a material for machining metal. Not having the equipment to exploit this material on an industrial scale, Osram sells the license to Krupp at the end of 1925. In 1926 Krupp brings sintered carbide onto the market under the name WIDIA (acronym and initialism">acronym An acronym is a word or name formed from the initial components of a longer name or phrase. Acronyms are usually formed from the initial letters of words, as in ''NATO'' (''North Atlantic Treaty Organization''), but sometimes use syllables, as ...
for = like diamond)." Machinery's Handbook gives the date of carbide tools' commercial introduction as 1927. Burghardt and Axelrod give the date of their commercial introduction in the United States as 1928. Subsequent development occurred in various countries. Although the marketing pitch was slightly
hyperbolic Hyperbolic is an adjective describing something that resembles or pertains to a hyperbola (a curve), to hyperbole (an overstatement or exaggeration), or to hyperbolic geometry. The following phenomena are described as ''hyperbolic'' because they ...
(carbides being not entirely equal to diamond), carbide tooling offered an improvement in cutting speeds and feeds so remarkable that, like
high-speed steel High-speed steel (HSS or HS) is a subset of tool steels, commonly used as cutting tool material. It is often used in power-saw blades and drill bits. It is superior to the older high-carbon steel tools used extensively through the 1940s in tha ...
had done two decades earlier, it forced
machine tool A machine tool is a machine for handling or machining metal or other rigid materials, usually by cutting, boring, grinding, shearing, or other forms of deformations. Machine tools employ some sort of tool that does the cutting or shaping. All ...
designers to rethink every aspect of existing designs, with an eye toward yet more rigidity and yet better
spindle Spindle may refer to: Textiles and manufacturing * Spindle (textiles), a straight spike to spin fibers into yarn * Spindle (tool), a rotating axis of a machine tool Biology * Common spindle and other species of shrubs and trees in genus ''Euony ...
bearings. During World War II there was a tungsten shortage in Germany. It was found that tungsten in carbide cuts metal more efficiently than tungsten in high-speed steel, so to economise on the use of tungsten, carbides were used for metal cutting as much as possible. The name became a
genericized trademark A generic trademark, also known as a genericized trademark or proprietary eponym, is a trademark or brand name that, because of its popularity or significance, has become the generic term for, or synonymous with, a general class of products ...
in various countries and languages, including English (widia, ), although the genericized sense was never especially widespread in English ("carbide" is the normal generic term). Since 2009, the name has been revived as a brand name by Kennametal, and the brand subsumes numerous popular brands of cutting tools. For the sake of clear communication, the reviving of the Widia brand may naturally further discourage use of the generic sense. Uncoated tips brazed to their shanks were the first form. Clamped indexable inserts and today's wide variety of coatings are advances made in the decades since. With every passing decade, the use of carbide has become less "special" and more ubiquitous. Regarding fine-grained hardmetal, an attempt has been made to follow the scientific and technological steps associated with its production; this task is not easy, though, because of the restrictions placed by commercial, and in some cases research, organisations, in not publicising relevant information until long after the date of the initial work. Thus, placing data in an historical, chronological order is somewhat difficult. However, it has been possible to establish that as far back as 1929, approximately 6 years after the first patent was granted, Krupp/Osram workers had identified the positive aspects of tungsten carbide grain refinement. By 1939, they had also discovered the beneficial effects of adding a small amount of vanadium and tantalum carbide. This effectively controlled discontinuous grain growth. What was considered 'fine' in one decade was considered not so fine in the next. Thus, a grain size in the range 0.5–3.0 μm was considered fine in the early years, but by the 1990s, the era of the nano-crystalline material had arrived, with a grain size of 20–50 nm.


Pobedit

''Pobedit'' ( rus, победи́т, link=no) is a sintered carbide alloy of about 90%
tungsten carbide Tungsten carbide (chemical formula: WC) is a chemical compound (specifically, a carbide) containing equal parts of tungsten and carbon atoms. In its most basic form, tungsten carbide is a fine gray powder, but it can be pressed and formed into ...
as a hard phase, and about 10%
cobalt Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, p ...
(Co) as a binder phase, with a small amount of additional carbon. It was developed in the
Soviet Union The Soviet Union,. officially the Union of Soviet Socialist Republics. (USSR),. was a List of former transcontinental countries#Since 1700, transcontinental country that spanned much of Eurasia from 1922 to 1991. A flagship communist state, ...
in 1929, it is described as a material from which
cutting tools In the context of machining, a cutting tool or cutter is typically a hardened metal tool that is used to cut, shape, and remove material from a workpiece by means of machining tools as well as abrasive tools by way of shear deformation. The majori ...
are made. Later a number of similar alloys based on tungsten and cobalt were developed, and the name of 'pobedit' was retained for them as well.the free dictionary: pobedit
/ref> Pobedit is usually produced by
powder metallurgy Powder metallurgy (PM) is a term covering a wide range of ways in which materials or components are made from metal powders. PM processes can reduce or eliminate the need for subtractive processes in manufacturing, lowering material losses and ...
in the form of plates of different shapes and sizes. The manufacturing process is as follows: a fine powder of tungsten carbide (or other refractory carbide) and a fine powder of binder material such as cobalt or nickel both get intermixed and then pressed into the appropriate forms. Pressed plates are sintered at a temperature close to the melting point of the binder metal, which yields a very tight and solid substance. The plates of this superhard composite are applied to manufacturing of metal-cutting and drilling tools; they are usually soldered on the cutting tool tips. Heat post-treatment is not required. The pobedit inserts at the tips of drill bits are still very widespread in Russia.


See also

* Carbide saw


References


Bibliography

* *


Further reading

* *


External links

{{Authority control Carbides Superhard materials Tungsten compounds Metalworking tools